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71.
In this study, springtime coastal currents along the Latium coast and their relation to external forcings, mainly wind stress curl and atmospheric pressure, are analysed. As a main result, we find that hydrographical measurements reveal currents parallel to the bottom isobaths, but with isopycnal sloping upwards towards the coast, suggesting the importance of upwellings in determining the coastal currents. This is confirmed by thermal satellite data showing the presence of a \sim10-km-wide patch of cold water east of Mount Argentario, i.e. a cyclonic vortex. The current meter data give rather small values of the time-averaged alongshore velocities (\sim2 cm s−1 for most current meters and \sim3 cm s−1 for the current meter placed immediately off the Argentario) and also smaller values for the offshore velocities. The correlation between these two types of currents is rather poor; this is also due to the variability characteristic of a wind-induced upwelling. Finally, we obtain a value of 0.74 for the correlation between the alongshore current (first mode of Empirical Orthogonal Functions decomposition) and the wind stress if a 23-h time lag is assumed.  相似文献   
72.
An omphacite from the Nybø eclogite pod, Norway, has a chemical composition which plots within the gap, often regarded as a miscibility gap, which is evident in all previous compilations of natural jadeite-rich acmite-poor omphacite compositions. Its cation site populations determined by crystal structure refinement accord well with its chemical composition analysed by electron microprobe. Its disordered space group C2/c symmetry extends the known compositional range of C2/c pyroxene. The postulated miscibility gap is regarded as real and wide at low temperatures, but it appears to narrow with increasing temperature or ultimately with increasing acmite proportion. The adjacent primitive symmetry field appears to initially widen with increasing temperature or increasing acmite proportion, at the expense of the diminishing miscibility gap, before finally closing with further increase.  相似文献   
73.
Summary Middle Triassic volcanic rock outcrops in the Mount Agnello area (Fiemme Valley, Italy) are examined in this study. Chemical analyses based on main and trace elements (Rb, Sr, Zr, Y, Nb) allow this volcanism to be defined as shoshonitic. The amphiboles, which occur with thick opacitic rims, were determined as ferroan pargasites. They were often found in volcanites of calcalkaline and/or shoshonitic associations. Consequently, this volcanism can be associated with a newly orogenized area undergoing stabilization. These data support the more recent studies on the mid-Triassic volcanism in the Southern Alps and underline the particular position of this magmatism in the tectonic evolution of this area.
Les roches volcaniques de l'aire de Mont Agnello (Vallèe de Fiemme, Italie): Une contribution à la connaissance du volcanisme du trias moyen des Alpes Meridionales
Résumé Sont examinées les volcanites du Trias moyen affleurantes dans l'aire de Mont Agnello (Vallèe de Fiemme, Italie). Les déterminations du chimisme, en particulier celles regardant les éléments en traces (Rb, Sr, Zr, Y, Nb), revèlent pour ce volcanisme une affinité shoshonitique qui est bien associable à une aire de recente orogenèse en voie de stabilisation. On a aussi analysé l'amphibole, present dans ces roches, caracterisé par d'epais bords de réaction et on l'à reconnu comme une pargasite riche en fer. Ces amphiboles ont été retrouvé fréquemment dans des volcanites d'association calcoalcaline et/ou shoshonitique.


With 4 Figures  相似文献   
74.
75.
The Jurassic N-MORB ophiolites of the Pineto Unit, which were unaffected by Alpine metamorphism, can be compared to the Apennine ophiolites. They are, however, distinguished by their cover rocks that include a silico-clastic flysch that we have dated as Albian–Cenomanian. Clastic deposits of the same type, but coarser grained, are known from the normal cover rocks of the Balagne Nappe E-MORB ophiolites, originally located on a thinned continental crust and/or near a continental margin. The Pineto Unit thus indicates that the detrital input of continental material was able to extend to a domain of clearly oceanic character in the Ligurian palaeo-ocean. To cite this article: M. Durand-Delga et al., C. R. Geoscience 337 (2005).  相似文献   
76.
This work describes a laboratory investigation of processes ruling the dissolution of galena (PbS) under conditions that mimic oxidising Earth surface environments. Freshly cleaved (001) galena surface was partially dissolved in solutions at different pH (HCl, pH between 1.2 and 5.8) and temperature (298 K) levels for several weeks in a flow-through reactor. Analysis of the galena surface after exposure to oxygen-saturated solutions was performed by XPS. The estimated thickness of surface layer formed after interaction for four weeks with solution at pH 5.8 was ∼0.5 nm. After the same time of interaction with solution at pH 1, the surface layer was at least 9 nm thick. Stationary dissolution rates were measured at different pH (between 1 and 5.8) and temperatures (298, 323, 348 K). Reaction order with respect to hydrogen ion averages 0.6 and slightly decreases with temperature. Dissolution rates, plotted vs. the reciprocal values of temperature, follow Arrhenius behaviour. Activation energies show a sharply discontinuous variation with pH. They are 13.5 ± 2 kJmol−1 at pH = 1.2 and 2.87, whereas at pH of 4.08, 4.7, and 5.8, they show, respectively, values of 48.8 ± 3.5, 45 ± 4, and 51 ± 4 kJmol−1. The apparent activation energy was also investigated by starting the experiment from pH 5.8 and then decreasing to pH 1.2. In this case, the apparent activation energies were 44 ± 4 kJmol−1 and 21 ± 4 kJmol−1, respectively.Apparent activation energies indicate a diffusion-controlled kinetic regime for pH <3, and a mixture of surface and diffusion control for pH between ∼4 and 5.8. A strong effect of solution pH on the mineral-water interface is revealed also by the observed pH dependence of surface-layer thickness. On the basis of the high-resolution XPS signals, the dependence of activation energies on solution pH should reflect a change of structure, and also chemical composition, of the mineral-water interface.  相似文献   
77.
In past years, seismic response of asymmetric structures has been frequently analysed by means of single-storey models, because of their simplicity and low computational cost. However, it is widely believed that use of more realistic multi-storey models is needed in order to investigate effects of some system characteristics (such as overstrength, higher modes of vibration, etc.) that make behaviour of multi-storey schemes different from that of single-storey systems. This paper examines effects of the overstrength in element cross-sections on the seismic behaviour of multi-storey asymmetric buildings. It is shown that in actual buildings this characteristic, which is sometimes very variable both in plan and along the height of the building, may lead to distributions of ductility demands different from those expected according to the results from single-storey models. Consequently, torsional provisions, which aim at reducing ductility demands of single-storey asymmetric systems to those of the corresponding torsionally balanced systems, should be re-checked in light of the behaviour of realistic multi-storey buildings.  相似文献   
78.
A joint inversion of both first and refracted arrivals is applied on a seismic line, acquired onshore, in order to obtain a well‐resolved velocity field for the computation of static corrections. The use of different arrivals in the inversion involves exploiting the information derived from the different raypaths associated with each wave type, thus enhancing the reliability of the inversion. The data was gathered by Saudi Aramco in an area of the Arabian Peninsula characterized by strong lateral variations, both in topography and shallow velocity, and where therefore a well‐defined near‐surface velocity field is important. In addition to velocity, the depth distribution of the quality factor Q is computed from the tomographic inversion of the seismic‐signal frequency shift. Thus, the Q‐factor field is used to perform an inverse Q‐data filtering and improve the resolution of the final stacked section.  相似文献   
79.
A conceptual-stochastic approach to short time runoff data modelling is proposed, according to the aim of reproducing the hydrological aspects of the streamflow process and of preserving as much as possible the dynamics of the process itself. This latter task implies preservation of streamflow characteristics at higher scales of aggregation and, within a conceptual framework, involves compatibility with models proposed for the runoff process at those scales. At a daily time scale the watershed response to the effective rainfall is considered as deriving from the response of three linear reservoirs, respectively representing contributions to streamflows of large deep aquifers, with over-year response lag, of aquifers which run dry by the end of the dry season and of subsurface runoff. The surface runoff component is regarded as an uncorrelated point process. Considering the occurrences of effective rainfall events as generated by an independent Poisson process, the output of the linear system represents a conceptually-based multiple shot noise process. Model identification and parameter estimation are supported by information related to the aggregated runoff process, in agreement to the conceptual framework proposed, and this allows parameter parsimony, efficient estimation and effectiveness of the streamflow reproduction. Good performances emerged from the model application and testing made with reference to some daily runoff series from Italian basins.  相似文献   
80.
The bulk composition, mineralogy and mineral chemistry of base-metal sulfides have been investigated in the Fe-Ni-(Cu) ore deposits of the Ivrea-Verbano basic complex.The sulfide ores mostly display textural evidence of having been primarily deposited as an immiscible melt. Bulk compositions of the ores indicate that considerably low Ni/Fe and Ni/Co ratios are found in deposits developed close to metasedimentary country rocks, possibly as a result of mixing with sedimentary sulfur.Phase relations of primary sulfides indicate that early crystallization of the ore was dominated by a monosulfide solid solution (Mss) with a pyrrhotite composition, from which pentlandite and chalcopyrite were formed through subsolidus exsolution. Pentlandite from contaminated ores is typically enriched in Co. Troilite and hexagonal intermediate pyrrhotite intergrowths frequently occur due to low-temperature equilibration of metal-rich pyrrhotites, suggesting a low S fugacity of the original sulfide melt.The sulfides may be locally mobilized and redeposited along shear zones within the same host rock, giving rise to fairly massive ores having a typical cemented-breccia texture. Bulk composition and assemblages suggest that mobilization occurred at various temperatures during the cooling history of the ore, when sulfides were still in the molten state or at a lower temperature under the influence of abundant deuteric fluids. In this last case, growth of pyrite is seen as being possibly due to sulfurization and/or oxidation.  相似文献   
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